The research group at the Department of Physics and Earth Sciences, University of Ferrara, specializes in non-destructive diagnostic techniques for cultural heritage artifacts, leveraging advanced X-ray and optical imaging laboratories. These facilities enable comprehensive analysis of paintings and small objects, supported by funding from the Department and INFN through the CHNet network.
X-ray radiography is performed on paintings and small artifacts, utilizing dedicated setups with minifocus and flat-panel detectors. In the LarixB laboratory, two large X-ray scanners are available for analyzing large paintings, over 2 meters while delivering high spatial resolution. These scanners enable detailed X-ray radiography, revealing subsurface features such as preparatory layers, pentimenti, and overpainting that are invisible to the naked eye. Small cultural heritage objects can also analyzed with X-ray radiography using dedicated setups. These systems produce high-resolution images that penetrate surface layers to map internal structures without harming the object.
Specialized software handles X-ray and CT data processing at the final stage, performing analysis, data extraction and CT 3D reconstructions. Advanced corrections address common artifacts, including beam hardening, metal artifacts, and ring artifacts for CT, ensuring accurate X-ray models.
X-ray fluorescence (XRF) characterizes elemental composition in paintings and heritage objects, employing portable systems like Bruker ARTAX with silicon drift detectors (SDD). Applications include pigment identification (e.g., Cu in azurite, Fe in earths, Hg in cinnabar) and analysis of the preparatory layer (e.g., Pb in lead white), with in-situ analysis supported by peak analysis software, including tools for peak deconvolution and correction of typical fluorescence phenomena such as escape peaks.
Multispectral imaging captures data across visible, infrared (reflectography), and UV fluorescence using CCD detectors, revealing underdrawings, pigments, and restoration layers.
Visible imaging uses high spatial resolution cameras with professional broadband light sources to capture detailed surface textures and color distributions in cultural heritage artifacts. Macrophotography offers high-magnification imaging (1:1 ratios or greater) via specialized lenses and high-resolution CCD sensors, revealing fine details, brushstrokes, and surface defects invisible to the naked eye. Raking light applies low-angle illumination from professional sources to highlight surface topography, including raised paint, canvas texture, retouches, craquelure and panel deformations. Transillumination transmits light through thin supports like canvas or paper to reveal underlying repairs, variations in paint thickness, and hidden damage.
Infrared reflectography (IRR) employs CCD sensors sensitive up to 1.1-1.3 μm, paired with optimized incandescent lamps emitting near-infrared radiation (roughly 760 nm to 2000 nm), to capture IR images that visualize preparatory underdrawings beneath paint layers in paintings and manuscripts. This non-destructive optical technique takes advantage of the partial transparency of many pigments and binders to near-IR light, allowing the radiation to penetrate the pictorial layer, reflect off the preparatory ground, and reveal hidden features like initial sketches, pentimenti (artist changes), signatures, dates, and underpaintings that are opaque in visible light. Its simplicity—requiring only standard or slightly modified cameras and common lighting—makes it highly practical for in-situ use, cost-effective and valuable for authentication, technique analysis, and restoration planning without risking damage to artifacts.
UV fluorescence imaging uses professional Wood lamps or UV flash systems paired with high-resolution CCD cameras to capture RGB images highlighting different pigments, varnishes, and retouches via characteristic colors (e.g., bright yellow for oils, salmon for zinc white, dark for modern retouches). This non-destructive method reveals varnish layers, differentiates binders/pigments (e.g., intense yellow for natural resins, weak for synthetics), and detects repairs darker due to less aging fluorescence, aiding restoration and authentication simply with portable, low-cost equipment.
Selected publications:
Brancaccio, R., Albertin, F., Seracini, M., Bettuzzi, M., & Morigi, M. P. (2023). A geometric feature-based algorithm for the virtual reading of closed historical manuscripts. Journal of Imaging, 9(10), 230.
Giuntini, L., et al. (2021). Detectors and cultural heritage: The INFN-CHNet experience. Applied Sciences, 11, 3462.
Albertin, F., Ruberto, C., Cucci, C., Callieri, M., Potenziani, M., Siotto, E., Pingi, P., Scopigno, R., Bettuzzi, M., Brancaccio, R., Morigi, M. P., Castelli, L., Taccetti, F., Picollo, M., Stefani, L., & de Vita, F. (2021). “Ecce Homo” by Antonello da Messina, from non-invasive investigations to data fusion and dissemination. Scientific Reports, 11, 95212.
Albertin, F., Morigi, M. P., Bettuzzi, M., Brancaccio, R., Macchioni, N., Saccuman, R., Quarta, G., Calcagnile, L., & Picchi, D. (2022). X-ray tomography unveils the construction technique of Un-Montu’s Egyptian coffin (Early 26th Dynasty). Journal of Imaging, 8(2), 39.
Brancaccio, R., Bettuzzi, M., Casali, F., Morigi, M. P., Levi, G., Gallo, A., Marchetti, G., & Schneberk, D. (2011). Real-time reconstruction for 3-D CT applied to large objects of cultural heritage. IEEE Transactions on Nuclear Science, 58(4), 1864-1871.
Ruberto, C., Mazzinghi, A., Massi, M., Castelli, L., Czelusniak, C., Palla, L., Gelli, N., Bettuzzi, M., Impallaria, A., Brancaccio, R., Peccenini, E., & Raffaelli, M. (2016). Imaging study of Raffaello's “La Muta” by a portable XRF spectrometer. Microchemical Journal, 126, 63-69.
Romani, M., Pronti, L., Sbroscia, M., Petrucci, F., Tarquini, O., Verona-Rinati, G., Ricci, M. A., Sodo, A., Colapietro, M., Marinelli, M., Pifferi, A., & Cestelli-Guidi, M. (2020). “St. Joseph with the Child” by Gian Lorenzo Bernini: A definitive artwork or a preparatory drawing? A multidisciplinary study of the only autograph painting of the Artist, preserved at Palazzo Chigi of Ariccia (Rome). Journal of Cultural Heritage, 46, 283-288
Impallaria A, Mazzacane S, Petrucci F, Tisato F, Volpe L. Portable X-ray fluorescence device reveals the artistic palette of Carlo Bononi, Baroque artist from Ferrara. X-Ray Spectrometry 2020; 49: 442–450